The 35-year-old, who has returned to the spotlight with single Love Made Me Do It, has ditched her long hair in favour of a short crop.
Turning heads, the mum-of-one wore a T-shirt dress with thigh high flat boots and a bright yellow raincoat.
During her appearance on the show, she opened up about the prospect of Girls Aloud reforming – saying they won’t be following in the footsteps of the Spice Girls.
"We reformed before and I think there's a limited amount of times that you can reform," she said.
"We had so much fun when we used to tour as Girls Aloud. We are older now. We have children. You can never say never but I don't think so right now. "
Cheryl released her first single in nearly four years at midnight last night, in which she sings how she has "fallen hard like a million times".
In the high-energy video, in which she dances in baggy thigh-high boots and a crop top, she sings: "I took the fast lane all of my life, I've been a bad girl, I've been a good wife.
"I don't stop to think, when I go in, I go in."
The song also details how her friends tell her to stop because "they're the ones who pick the pieces up", adding: "It's bad for my health but I just can't help myself."
The singer also dances with black-clad male dancers and shows off a cropped hairstyle as she sings: "Oh my god I'm such a sucker, I fall in love with every f*****. Oh no I won't apologise."
She ends the video by winking at the camera and whispering: "And I'd do it again."
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