The 23-year-old showcased her alter-ego Ember for the steamy lingerie shoot in which she cut a striking figure with her red hair.
Coutney shaved her head following her devastating miscarriage two years ago and has since worn blonde wigs, but as she prepares to release new music, she is embracing a distinctly more fiery side.
In the steamy shots she wore a white lace bra and thong and posed bare foot on railway tracks, while in others she looked seductively into the camera.
The new look comes six weeks after filing for divorce from Doug Hutchinson, 57, whom she married when she was 16.
Opening up about the split on Instagram, Courtney wrote, "This day marks a new chapter in my life.
"It's a lot scary and a little surreal, but all change is.
"Praying having faith and hope in the destiny God has created for me. #picoftheday #newchapter #divorce #breathing."
It was only two months before that Courtney begged Doug to take her back.
She wrote on Instagram alongside a picture of them on their wedding day in 2011: "I need this man back in my life.
"I need him to come help me. I need him to want our marriage to work.
"He's been my only solid rock.
"Doug, if you read this – this is a public cry for your undying love. I need you."
Courtney, who appeared on Celebs Go Dating last year, recently opened up about depression.
Sharing a screenshot from Snapchat of herself crying with the text: "Depression is hard to kick.
"But I'll get through it and so will you if you're a sufferer," written across it.
She added in the caption, "I feel so much.
"I soak up too much energy from myself and others.
"I love too deeply. I'm extremely insecure. Terribly childlike and vulnerable.
"This is me and my struggle with depression. But I have faith I'll prevail.
"If you're a sufferer of anxiety or depression – know that you aren't alone."
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