George, 26, wrapped his arm around Olivia's shoulders and whispered into her ear as they sat beside each other in London's Libertine nightclub.
The son of football legend Gary couldn't take his eyes of the blonde beauty, 26, who wowed in a green crop top and ripped jeans.
At one point George even made a suggestive gesture which made Olivia giggle.
A source told The Sun Online: “George couldn’t keep his hands off Olivia, he kept putting his arm around her and Liv seemed to be into it.
"She was out with Love Island pal Amber, but she looked happy to continue chatting to just George for most of the night. At one point he even did made a sexually suggestive gesture at her, so things might have been getting a bit more raunchy as the night went on.”
“In the bathroom Olivia also seemed to be telling Amber that she didn’t want to be filmed for social media earlier on, making it seem that she didn’t want people to see her flirting with George.”
However, an insider told us the pair go way back and are just friend, saying: "They are childhood friends and went to school together. He is like her brother.”
The Sun Online has contacted representatives for Liv and George for comment.
Olivia and George's flirty behaviour comes after she sparked rumours she'd split from Bradley Dack after they unfollowed each other on social media.
The Love Island star posted a tweet just after midnight suggesting she and the Blackburn Rovers footballer, 24, had ended things.
In a now deleted post, she said: “Ok I tried??♀”
Olivia attended the BooHoo Stefflon Don party at Libertine with mates Amber Davies and Lottie Moss.
One of ex Chris Hughes’s latest love interests Emily Blackwell from Made In Chelsea was also there
Earlier this week Olivia had told a glossy magazine she was back with her ex Bradley.
It came after she had hinted they were giving things another go when she enjoyed a romantic spa break with the footballer and then got a tattoo of Bradley’s shirt number, 23.
She said. “We’re seeing each other. It’s going well. Bradley makes me really happy, I lost my identity with Chris but I feel like I’m getting it back now.
“I’m hopeful that it’ll turn into something more serious, but I’m hesitant to put a label on it at the moment.”
It’s not the first time Olivia has aired her dirty laundry on Twitter with Bradley.
In February, while with Chris, 25, she sent early morning messages to him after a night on the town.
She wrote “yellow suits you”, “hey” and “fatty” in response to a video of the Blackburn Rovers footballer wearing a yellow training top.
Shortly after the blonde beauty and Chris broke up with scenes later aired on their show Crackin’ On.
She recently revealed how she was struggling to trust Chris because he was always checking his phone.
Olivia said: “I never trusted him. I think he messaged a few different women while we were together.”
And Chris revealed last week to the Sun’s Bizarre column he has no feelings for her.
He said: "I haven’t put anything out there or documented my emotions towards it because I don’t feel anything for Olivia anymore."
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